Sergi Arfelis, Irene Malpartida, Valentin Lair,Vincent Caldeira, IlijaSazdovski, Alba Bala, Pere Fullana-i-Palmer

The world's energy transition from fossil to renewable energy is unthinkable without further research in energy storage. Decreasing the environmental impacts from the production of energy storage technologies is essential for achieving a green energy transition. Calcium Zincate (CAZN) is used as active material in rechargeable zinc-based batteries (and other products, such as heterogeneous catalysts for biodiesel or antifungal products). They present a low-cost, safer, alternative to Lithium based batteries and are targeted as replacement solutions for lead-acid batteries.

We propose a novelty in the synthesis of CAZN, the hydro-micro-mechanical process (HMMS). The residence time of this new route is about 20 times lower than the traditional processes, so its production needs less infrastructure and can deliver quicker at an industrial scale. In addition, laboratory tests indicate that HMMS CAZN has more reaction surface area and the activation of the battery is 1.77 times faster.

Using the life cycle assessment (LCA) method, we compare this new process with the current best option, hydro-thermal synthesis (HTS). The cradle-to-gate results per kg of CAZN already indicates that HMMS is an environmentally better alternative for all indicators; especially when considering the normalization of the results with the residence time and the surface area, HMMS delivers better results, with improvements of 97 % in global warming, for instance. With this, we demonstrate that, outside of the cradle-to-gate, variables that make the final products better service units or give more function should be considered as valuable additional information when deciding among alternatives. This also highlights the importance of life cycle thinking when working with chemical processes and substances.

In the sensitivity analysis, we developed 7 scenarios related to the energy demand of the processes, and we incorporated the projection in the European electricity mix for 2030 and 2050.

Delgado-Aguilar, M., Puig, R., Sazdovski, I., Fullana-i-Palmer, P., (2020)

Circular economy comes to break the linear resource to waste economy, by introducing different strategies, two of them being: using material from renewable sources and producing biodegradable products. The present work aims at developing polylactic acid (PLA), typically made from fermented plant starch, and polycaprolactone (PCL) blends, a biodegradable polyester, to study their potential to be used as substitutes of oil-based commodity plastics. For this, PLA/PCL blends were compounded in a batch and lab scale internal mixer and processed by means of injection molding. Tensile and impact characteristics were determined and compared to different thermoplastic materials, such as polypropylene, high density polyethylene, polystyrene, and others. It has been found that the incorporation of PCL into a PLA matrix can lead to materials in the range of 18.25 to 63.13 megapascals of tensile strength, 0.56 to 3.82 gigapascals of Young’s modulus, 12.65 to 3.27 percent of strain at maximum strength, and 35 to 2 kJ/m2 of notched impact strength. The evolution of the tensile strength fitted the Voigt and Reuss model, while Young’s modulus was successfully described by the rule of mixtures. Toughness of PLA was significantly improved with the incorporation of PCL, significantly increasing the energy required to fracture the specimens. Blends containing more than 20 wt% of PCL did not break when unnotched specimens were tested. Overall, it was found that the obtained PLA/PCL blends can constitute a strong and environmentally friendly alternative to oil-based commodity materials.

This study presents a method based on life cycle assessment to reduce and simplify the decision-making process and to identify the best available techniques of a product. This procedure facilitates the selection of a technical alternative from an environmental point of view and the reduction of emission levels and the consumption of energy and primary resources. This method comprises the following four steps: (i) the identification of the current techniques of a specific product, (ii) the application of a life cycle assessment to determine the hot spots, (iii) the proposal of the best available techniques and (iv) the development of a best available techniques reference document (step not implemented in our case study). The Cantabrian anchovy canning industry is selected as a case study due to the importance of this sector from economic, social and touristic points of view. An entire life cycle assessment of one can of anchovies in extra virgin olive oil is conducted. The results indicated that the hot spots of the life cycle were the production of aluminium cans (for packaging) and extra virgin olive oil and the management of the packaging waste. According to these results, the study proposes several improvements, such as packaging recycling and several best available techniques for the canned anchovy product.

One of the main drivers for companies to perform environmental improvements is economic benefit, either by obtaining a more valuable product or gaining new customers. Circular economy combines environmental improvements with these drivers to achieve higher and quicker benefits. This paper is a case study on packaging eco-design aligned with circular economy strategy along the production chain. Life cycle assessment (LCA) was used to identify the product life cycle stages where the application of eco-design strategies would be more efficient (in this case, raw materials production from virgin petrochemicals). To improve the environmental profile of this packaging, virgin petrochemicals were partially replaced by mineral fillers (calcium carbonate based) or/and post-consumer recycled plastics. Different technically compliant cosmetic tubes were produced by collaboration between a company producing the plastic granulates with mineral fillers and a company producing the cosmetic tubes and cradle-to-gate LCA were performed. The replacement of virgin petrochemicals by mineral fillers helped to reduce the environmental impacts by an average of 12% and the use of post-consumer recycled plastic further decreased emissions up to 29% for 6 out of the 9 evaluated impact categories. The option with better environmental performance was also the one with lower economic costs.

According to the involved companies, LCA combined with ecodesign helped to achieve efficient environmental and economic savings. The findings are important for the plastic packaging sector because they tackle with prime concerns, like plastic debris, climate change and resource depletion. They are of main interest for industrial activities where brand positioning is a priority (i.e. cosmetics).

El objetivo del proyecto es evaluar los impactos ambientales de los compuestos plásticos con aditivos minerales a través del uso de metodología ACV mejorada. La aplicación de los compuestos a diferentes aplicaciones de envasado de alimentos se analiza a lo largo del ciclo de vida de las mismas.

El objetivo del proyecto es fomentar la ecoinnovación y la mejora medioambiental de la fabricación de productos de arcilla para la construcción, al mismo tiempo que aumenta la competitividad de este sector en España. El resultado principal del proyecto incluye el desarrollo de una herramienta para ayudar a los productores españoles de materiales a base de arcilla para la construcción a obtener Declaraciones Ambientales de Producto (DAP) de manera rentable.

El objetivo general del proyecto es desarrollar una herramienta simplificada que permita a los fabricantes de productos cerámicos estructurales obtener Declaraciones Ambientales de Producto (DAP) de una manera más rápida y competitiva. El objetivo es promover la ecoinnovación y la mejora medioambiental en la fabricación de los productos cerámicos y aumentar la competitividad del sector español de cerámica estructural.